Keywords

post-transition symmetry, phase transition, isotropy, NANO3

Abstract

Predictions of the possible post-transition symmetries of an R 3c zone center continuous phase transition are made using recent extensions of the Landau theory. The Landau theory is summarized and direct group theoretical methods are applied to the R 3c phase. General techniques for solving systems of nonlinear polynomial equations are reviewed and these techniques are applied to the minimization of the free energy F for the aforementioned possible symmetries. The results of the direct methods and the minimization procedures are shown to be compatible. It is shown that the transition to R 3c in NaNO3 is consistent with the above results as well as with the observed atomic displacements.

Original Publication Citation

Stornetta, Scott W. and Dorian M. Hatch."Isotropy group description of a phase transition in NaNO[sub 3]." The Journal of Chemical Physics 8 (1984): 5745-575.

Document Type

Peer-Reviewed Article

Publication Date

1984-06-01

Permanent URL

http://hdl.lib.byu.edu/1877/1310

Publisher

AIP

Language

English

College

Physical and Mathematical Sciences

Department

Physics and Astronomy

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