Keywords
Nitric Oxide, Coal, Reburning, Model
Abstract
An investigation of a global reburning-NO reaction, sum(CiHj) + NO => HCN + . . ., which is a reduction pathway of nitric oxide (NO) by reaction with gaseous hydrocarbons, was conducted. The global reburning-NO rate expression was deduced from a combination of elemental reactions. The global rate expression and its rate constants were then determined by correlating predicted species profiles from simple hydrocarbon flames. This global reburning-NO rate constant can be expressed as 2.7x106 exp(-18,800/RT) (gmol/cm3 s). This expression and constants are applicable to atmospheric pressure with an equivalence ratio range of 1.0-2.08 for light hydrocarbon reburning gases (CH4 and C2H4).
Original Publication Citation
Chen, W., L. D. Smoot, S. C. Hill, and T. H. Fletcher, “Global Rate Expression for Nitric Oxide Reburning. Part 2,” Energy and Fuels, 10, 1046-1052 (1996).
BYU ScholarsArchive Citation
Chen, Wei; Smoot, L Douglas; Hill, Scott C.; and Fletcher, Thomas H., "Chen, W., L. D. Smoot, S. C. Hill, and T. H. Fletcher, “Global Rate Expression for Nitric Oxide Reburning. Part 2,” Energy and Fuels, 10, 1046-1052 (1996)." (1996). Faculty Publications. 7062.
https://scholarsarchive.byu.edu/facpub/7062
Document Type
Peer-Reviewed Article
Publication Date
1996
Publisher
American Chemical Society
Language
English
College
Ira A. Fulton College of Engineering
Department
Chemical Engineering
Copyright Status
© 1996 American Chemical Society
Copyright Use Information
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