Keywords

Covariance and correlation, Genomics, Probability theory, Interpolation, Hydrodynamics simulations, Polymer solution flows, Monte Carlo methods, Nanochannels, Crankshafts, Computer simulation

Abstract

Using Monte Carlo simulations of a touching-bead model of double-stranded DNA, we show that DNA extension is enhanced in isosceles triangular nanochannels (relative to a circular nanochannel of the same effective size) due to entropic depletion in the channel corners. The extent of the enhanced extension depends non-monotonically on both the accessible area of the nanochannel and the apex angle of the triangle. We also develop a metric to quantify the extent of entropic depletion, thereby collapsing the extension data for circular, square, and various triangular nanochannels onto a single master curve for channel sizes in the transition between the Odijk and de Gennes regimes.

Original Publication Citation

Biomicrofluidics 7, 024102 (2013); https://doi.org/10.1063/1.4794371

Document Type

Peer-Reviewed Article

Publication Date

2013-03-01

Publisher

American Institute of Physics

Language

English

College

Ira A. Fulton College of Engineering

Department

Chemical Engineering

University Standing at Time of Publication

Assistant Professor

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