free radicals, irradiated, potassium hydroxylamine disulfonate
Two free radicals formed when single crystals of potassium hydroxylamine disulfonate are irradiated with gamma rays at 77degrees K were studied by ESR. The ESR spectra result from a predominant center (radical A) exhibiting large 14N and 1H hyperfine splittings and from lesser amounts of Fremy's radical [O-dotN(SO3)2-2]. The g and hyperfine tensors of these radicals have been evaluated and are discussed. Radical A, whose identity remains in doubt, may be regarded as the precursor to Fremy's radical; on warming its lines decay and those of Fremy's radical are formed. Lines from radical A decrease in strength and those of the hydroxyl radical (O=dotH) grow in strength when irradiated crystals are photolyzed at 77degrees K. The reverse reaction occurs in the dark; the hydroxyl radical disappears and radical A is reformed.
Original Publication Citation
Holmberg, Robert W. and B. J. Wilson."ESR study of free radicals in irradiated single crystals of potassium hydroxylamine disulfonate." The Journal of Chemical Physics 61 (1974): 921-925.
BYU ScholarsArchive Citation
Wilson, B. J. and Holmberg, Robert W., "ESR study of free radicals in irradiated single crystals of potassium hydroxylamine disulfonate" (1976). All Faculty Publications. 778.
Physical and Mathematical Sciences
Chemistry and Biochemistry
© 1974 American Institute of Physics. This article may be downloaded for personal use only. Any other use requires prior permission of the author and the American Institute of Physics. The following article appeared in The Journal of Chemical Physics and may be found at http://link.aip.org/link/?JCPSA6/61/921/1
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