Keywords

heats of transport, diffusion, thermoeffect measurements

Abstract

Measurements of heats of transport are reported for binary liquid mixtures containing carbon tetrachloride and benzene, toluene, 2-propanone, n-hexane, or n-octane at 298 K and ambient pressure. Additionally, measurements were made at 308 K for carbon tetrachloride with benzene, toluene, and 2-propanone. The corresponding heat-mass Onsager coefficients are also reported, from which thermal diffusion ratios have been calculated based on Onsager reciprocity. These data will be used in a companion paper to report a modified Enskog method for correlation and prediction of heats of transport.

Original Publication Citation

Yi, S. C. and R. L. Rowley. "Heats of transport from diffusion thermoeffect measurements on binary liquid mixtures of carbon tetrachloride with benzene, toluene, 2-propanone, n-hexane, and n-octane." The Journal of Chemical Physics 87 (1987): 728-7213

Document Type

Peer-Reviewed Article

Publication Date

1987-12-15

Permanent URL

http://hdl.lib.byu.edu/1877/1461

Publisher

AIP

Language

English

College

Ira A. Fulton College of Engineering and Technology

Department

Chemical Engineering

Share

COinS