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Journal of Undergraduate Research

Keywords

salt concentrations, A. vinelandii nitrogenase, N2, electron source

College

Physical and Mathematical Sciences

Department

Chemistry and Biochemistry

Abstract

We are investigating the kinetic effect of salt concentration on the reaction N2 + (6+2n)H+ + (6+2n)e- + 2(6+2n)ATP ­ 2NH3 + nH2 + 2(6+2n)Pi + 2(6+2n)ADP (1) catalyzed by nitrogenase where the spontaneous decomposition of S2O4 2- is the electron source. Under high partial pressures of N2, n has a limiting value of one, but in the absence of N2, nitrogenase simply catalyzes the reduction of protons to H2.

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Chemistry Commons

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