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Journal of Undergraduate Research

Keywords

calorimitry data tracking, organic water contaminants, Cavitand [Co412]-8

College

Physical and Mathematical Sciences

Department

Chemistry and Biochemistry

Abstract

Cavitand [Co412]-8 is a cage-like molecule having an inner cavity with a volume of approximately 1375 Å that traps small organic molecules. The “1” in the chemical formula represents resorc[4]arene, a bowl-shaped molecule1. Two resorc[4]arenes are connected with four cobalt molecules to form the cavitand [Co412]-8. Experiments were conducted in which resorc[4]arene was mixed with a small organic guest, then cobalt was added to connect the cage and trap the organic guests. These experiments were conducted in a calorimeter and the heat of the reaction was measured. From this data one is able to calculate the heat released during encapsulation and to formulate a hypothesis as to the mechanism of binding.

Included in

Chemistry Commons

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